I found this very interesting article about smoothing PLA.Â
They are using Ethyl Acetate in a vapor bath the same way as acetone is used for ABS.
It seems to be working very well enough for home use.
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Here is a PLA octopus before and after smoothing.
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The original article is below with the exact method they used.
http://fabsterdam.com/3dprinting/smoothing-pla/